A disk census for the nearest group of young stars: Mid-infrared observations of the TW Hydrae Association

A group of young, active stars in the vicinity of TW Hydrae has recently been identified as a possible physical association with a common origin. Given its proximity ($\sim$50 pc), age ($\sim$10 Myr) and abundance of binary systems, the TW Hya Association is ideally suited to studies of diversity and evolution of circumstellar disks. Here we present mid-infrared observations of 15 candidate members of the group, 11 of which have no previous flux measurements at wavelengths longer than 2$\mu$m. We report the discovery of a possible 10$\mu$m excess in CD -33$^{\circ}$7795, which may be due to a circumstellar disk or a faint, as yet undetected binary companion. Of the other stars, only TW Hya, HD 98800, Hen 3-600A, and HR 4796A -- all of which were detected by IRAS -- show excess thermal emission. Our 10$\mu$m flux measurements for the remaining members of the Association are consistent with photospheric emission, allowing us to rule out dusty inner disks. In light of these findings, we discuss the origin and age of the TW Hya Association as well as implications for disk evolution timescales.Comment: 10 pages and 1 PostScript figure, accepted for publication in The Astrophysical Journal Letter

The radical cation of bacteriochlorophyll b. A liquid-phase endor and triple resonance study

The previous termradical cationnext term of bacterioehlorophyll b (BChl b) is investigated by ENDOR and TRIPLE resonance in liquid solution. The experimental hyperfine coupling constants, ten proton and three nitrogen couplings, are compared with the predictions from advanced molecular-orbital calculations (RHF INDO/SP). The detailed picture obtained of the spin density distribution is a prerequisite for the investigation of the primary electron donor previous termradical cationnext term in BChl b containing photosynthetic bacteria

Structural model correlation using large admissible perturbations incognate space

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76957/1/AIAA-10863-901.pd

Theoretical backgrounds of durability analysis by normalized equivalent stress functionals

Generalized durability diagrams and their properties are considered for a material under a multiaxial loading given by an arbitrary function of time. Material strength and durability under such loading are described in terms of durability, safety factor and normalized equivalent stress. Relations between these functionals are analysed. We discuss some material properties including time and load stability, self-degradation (ageing), and monotonic damaging. Phenomenological strength conditions are presented in terms of the normalized equivalent stress. It is shown that the damage based durability analysis is reduced to a particular case of such strength conditions. Examples of the reduction are presented for some known durability models. The approach is applicable to the strength and durability description at creep and impact loading and their combination

Families' social backgrounds matter : socio-economic factors, home learning and young children's language, literacy and social outcomes

Parental support with children's learning is considered to be one pathway through which socio-economic factors influence child competencies. Utilising a national longitudinal sample from the Millennium Cohort Study, this study examined the relationship between home learning and parents' socio-economic status and their impact on young children's language/literacy and socio-emotional competence. The findings consistently showed that, irrespective of socio-economic status, parents engaged with various learning activities (except reading) roughly equally. The socio-economic factors examined in this study, i.e., family income and maternal educational qualifications, were found to have a stronger effect on children's language/literacy than on social-emotional competence. Socio-economic disadvantage, lack of maternal educational qualifications in particular, remained powerful in influencing competencies in children aged three and at the start of primary school. For children in the first decade of this century in England, these findings have equity implications, especially as the socio-economic gap in our society widens

Practical Root Cause Analysis Of Connecting Rod Bushing Failures In A New Reciprocating Compressor And The Theory Behind The Failure Mechanism.

Case Stud

ESR, ENDOR and TRIPLE resonance studies of the primary donor radical cation P960+ in the photosynthetic bacterium Rhodopseudomonas viridis

The light-induced radical cation of the primary electron donor P960+• in photosynthetic reaction centers from Rhodopseudomonas viridis has been investigated by ESR, ENDOR and TRIPLE techniques. Both the comparison with the cation radical of monomeric bacteriochlorophyll b (BChl b) and with molecular-orbital calculations performed on P960+• using the results of an X-ray structure analysis, consistently show an asymmetric distribution of the unpaired electron over the two BChl b molecules which constitute P960+•. The possible relevance of this result for the primary electron transfer step in the reaction center is briefly discussed

Evidence for ubiquitous carbon grain destruction in hot protostellar envelopes

Earth is deficient in carbon and nitrogen by up to ${\sim}4$ orders of magnitude compared with the Sun. Destruction of (carbon- and nitrogen-rich) refractory organics in the high-temperature planet forming regions could explain this deficiency. Assuming a refractory cometary composition for these grains, their destruction enhances nitrogen-containing oxygen-poor molecules in the hot gas ($\gtrsim 300$K) after the initial formation and sublimation of these molecules from oxygen-rich ices in the warm gas (${\sim}150$K). Using observations of $37$ high-mass protostars with ALMA, we find that oxygen-containing molecules (CH$_3$OH and HNCO) systematically show no enhancement in their hot component. In contrast, nitrogen-containing, oxygen-poor molecules (CH$_3$CN and C$_2$H$_3$CN) systematically show an enhancement of a factor ${\sim} 5$ in their hot component, pointing to additional production of these molecules in the hot gas. Assuming only thermal excitation conditions, we interpret these results as a signature of destruction of refractory organics, consistent with the cometary composition. This destruction implies a higher C/O and N/O in the hot gas than the warm gas, while, the exact values of these ratios depend on the fraction of grains that are effectively destroyed. This fraction can be found by future chemical models that constrain C/O and N/O from the abundances of minor carbon, nitrogen and oxygen carriers presented here.Comment: Accepted for publication in ApJ Letter